Solder
for microwave assemblies
Updated June 22,
2005
Soldering is more of a material
science than anything else, and an excellent example of a case where
"what you don't know will hurt you". There are
experts in this field, we don't claim to be in that category. But
in the case of microwave engineering, or any other electronics industry,
a rudimentary knowledge of soldering issues is essential to success.
Further down this page we provide
a solder chart based on information provided
by Indium Corporation's web
site. They were kind enough to send us an update on February 12,
2004 (thanks Rick!) but we haven't checked our list against the
new list yet. Indium is based in Utica, New York. If you ever visit
Indium Corporation, be sure to take the tour of Utica's crown jewel,
the Matt Brewing
Company (anyone else remember Utica Club's Schultz
and Dooley talking beer stein commercials? Those Dudes were
cool but are no longer politically correct!) Check out the "Application
Notes" section on Indium Corporation's web site--there's more
information there than you ever knew existed about solders and solder
pastes. Where did they get the idea for the name of their Soldering101
application note? We wish we had thought of that! Indium Corporation
is to solder as Xerox is to copiers... without the bankruptcy rumors!

As on other Microwaves101 web
pages, here is a clickable index to this page on soldering:
Soldering
terminology
Some basic
solders
Indium Corporation's
solder chart
Soldering
terminology
Below some solder-related terminology
is defined; studying it will help you achieve microwave good-old-boy
status in your assembly shop. We must acknowledge Indium Corporations's
web site again here, providing us with excellent reference material.
Alloys
An alloy is a mixture of two or more elemental metals. Its melting
temperature (surprise!) is often lower than the melting temperature
of its ingredients.
Fusible
alloys
Solders that have liquidus temperatures below room temperature (kind
of like mercury, but maybe not as poisonous to fish) are called
fusible alloys. These are not often used in microwave engineering
but we left them in the solder table for completeness.
Intermetallics
intermetallics are layers of different materials that form when
you join dissimilar metals together using welding, brazing or soldering.
Sometimes a good thing, but sometimes a bad thing.
Welding
Welding is a very high temperature process, usually for joining
"like" metals. Both surfaces must be slightly melted to
form the bond, and the filler material (such as a welding rod in
an arc welder, or the wire in a wire-welder) is composed of a material
of similar melting point to the bonded surfaces. Industrial welding
requires wearing special goggles because materials glow brightly
at weld temperatures. Fluxes or forming gases (such as inert argon)
are essential to preventing oxidation during the welding operation.
Brazing
Brazing is a lower temperature process than welding, where intermetallics
are formed to create a bond, but still over 350 degrees C. The filler
material typically has a much lower melting point than the bonded
surfaces. A typical braze filler material is bronze. You may hear
the word "braze" when very high temperature solders such
as gold-germanium are used to bond feedthroughs into a hermetic
housing, its eutectic is 356 degrees C.
Soldering
Soldering is a lower temperature process than brazing. Only the
filler material, most often an alloy, is melted to create the bond.
Some intermetallics may be present in the bond as molecules of the
bonded surfaces leach off into the joint, which in some cases serves
to weaken the joint rather than strengthen it. For example, when
soldering gold surfaces using tin-based solder, you have to ask
your plating shop to restrict the gold thickness to perhaps 15 to
30 micro-inches, or your joint may fail after many temperature cycles.
Liquidus
Liquidus refers to the temperature at which a solder melts.
Solidus
Solidus refers to the temperature that a solder re-solidifies.
Eutectic
A eutectic alloy is one which melts and solidifies at the same temperature.
If the liquidus temperature in the solder table below ends in "E"
the solder is eutectic.
Percentage IACS
The solder chart below references the conductivity of each material
to that of copper, which is 1.72 micro-ohm centimeters.
Wetting and sweating
Wetting refers to the quality of a solder joint. In a good solder
joint, the solder will appear shiny (like it is wet) as opposed
to dull. A bad solder joint is often referred to as a "cold
joint". Sweating is a slang term for soldering.
Solder paste, versus sheet,
versus wire form
Solder can be procured in many forms. In paste form, the solder
alloy is powdered and suspended in a flux. The paste can then be
stenciled onto a printed circuit board, components placed over the
paste, and the board sent through a reflow furnace to effect the
solder joint.
Sheet solder, also called ribbon
or foil, is available in different thicknesses, and is used in applications
where a large area joint must be obtained, such as when a substrate
is solders to a backplane or housing. When a sheet is cut to a particular
shape of the item being soldered, the piece of solder is called
a preform. For high-volume jobs, you can have solder vendors
deliver preforms, saving you hours of "fun" with an Exacto
knife.
Wire solder is used in manual
"wiring jobs", and typical wire solders contain a core
of flux so that you have one less mess on your lab bench.
Lead content
The EU (European Union) has advised manufacturers that all electronics
assemblies must be lead-free by January 2006. Why? Because lead
in our environment has erased billions of IQ points from the present
generations of homo sapiens. What does this mean? There is a ton
of money being spent to develop cheap lead-free solders. And the
price of alternative materials may skyrocket on the commodities
market...
Fluxes
Flux is a material that is used to remove oxides from the metal
surfaces you are joining. Oxides are your enemy in obtaining a good
joint, you will never achieve a good joint without clean, oxide-free
surfaces. There are many types of fluxes, you should consult a soldering
expert on which one is right for your application.
Forming
gases
Like fluxes, forming gasses are used to prevent oxidation during
soldering operations, especially if a "fluxless" joint
is required (as is often the case in micro-electronics). Flux might
not kill your integrated circuit right away, but some of it may
end up trapped and cause your part to fail later.
Some
basic solders you might encounter in your lab
PbSn 60/40 widely available (you'll
find it at Radio Shack) and is used for many "wiring jobs".
It comes in a variety of diameters, and has low liquidus and solidus
temperatures (188C and 183C). It usually has a flux core, so anyone
can make a good joint with little training. Not suitable for microelectronics,
since it needs flux.
Indalloy #7 is a great low-temperature
solder.
Au/Sn 80/20 is a gold-based eutectic
solder used in many microelectronic applications. It does not need
flux, but performs best under a forming gas such as nitrogen or
hydrogen. Forming gases are used to displace oxygen so that no oxidation
occurs during the soldering process. Be careful around hydrogen
remember what happened to the Hindenburg!
One last piece of advice: remember
to shut off that soldering iron when you go home, so you don't burn
the place down!
Indium
Corporation's solder chart
|
Indalloy
#
|
Temp.
Liquidus C
|
Temp.
Solidus C
|
Composition
|
Mechanical
Properties
|
Notes
|
|
|
|
|
|
Mass
Density (gr/cc)
|
Electrical
Conductivity (% of IACS)
|
Thermal
Conductivity (W/cm-C @85C)
|
Thermal Coefficient
of Expansion (ppm/C @
20C)
|
|
| 46L |
8 |
7 |
61Ga
25In
13Sn
1Zn |
6.5 |
-- |
-- |
-- |
Alloy
liquid @rm.temp, wets glass and quartz. Mercury replacement. |
| 51 |
11E |
11 |
62.5Ga
21.5In
16Sn |
6.5 |
-- |
-- |
-- |
Alloy
liquid @rm.temp, wets glass and quartz. Mercury replacement. |
| 60 |
16E |
16 |
75.5Ga
24.5In |
6.35 |
-- |
-- |
-- |
Alloy
liquid @ room temp., wets glass and quartz. Mercury replacement. |
| 117 |
47E |
47 |
44.7Bi
22.6Pb
19.1In
8.3Sn
5.3Cd |
9.16 |
4.5 |
0.15 |
25 |
General
purpose fusible alloy. |
| 136 |
58E |
58 |
49Bi
21In
18Pb
12Sn |
9.01 |
2.43 |
0.1 |
23 |
General
purpose fusible alloy. Wettability not outstanding. For use
as solder. |
| 19 |
60E |
60 |
51In
32.5Bi
16.5Sn |
7.88 |
3.3 |
-- |
22 |
Environmentally
safe fusible alloy. Contains no lead or cadmium. |
| 158 |
70E |
70 |
50Bi
26.7Pb
13.3Sn
10Cd |
9.58 |
4 |
0.18 |
22 |
Lowest
melting point solder. |
| 162 |
72E |
72 |
66.3In
33.7Bi |
7.99 |
-- |
-- |
-- |
Environmentally
safe fusible alloy. Contains no lead or cadmium. |
| 174 |
79E |
79 |
57Bi
26In
17Sn |
8.54 |
-- |
-- |
-- |
Environmentally
safe fusible alloy. Contains no lead or cadmium. |
| 8 |
93E |
93 |
44In
42Sn
14Cd |
7.46 |
-- |
0.36 |
24 |
General
purpose fusible alloy. |
| 42 |
96E |
96 |
46Bi
34Sn
20Pb |
8.99 |
-- |
-- |
-- |
Bismuth
added to achieve a low melting point. Fair wettability. |
| 224 |
108E |
108 |
52.2In
46Sn
1.8Zn |
7.27 |
-- |
-- |
-- |
Pb
free solder, high dross due to Zn. |
| 1E |
118E |
118 |
52In
48Sn |
7.3 |
11.7 |
0.34 |
20 |
Indium-tin
eutectic with sharp melting point. Has good wettability on glass,
quartz and many ceramics. Has good low temperature malleability
and therefore compensates for some difference in coefficient
of expansion when dissimilar materials are soldered. |
| 255 |
124E |
124 |
55.5Bi
44.5Pb |
10.44 |
4 |
0.04 |
-- |
General
purpose fusible alloy. |
| 281 |
138E |
138 |
58Bi
42Sn |
8.56 |
4.5 |
0.19 |
15 |
Good
low melting point solder for electronics assembly of for applications
where Cd and Pb are to be avoided, and for thermo-electric applications.
Shear rate sensitive. |
| 290 |
143E |
143 |
97In
3Ag |
7.38 |
23 |
0.73 |
22 |
Indium
with silver added to improve strength. Has the wettability and
low-temperature malleability of indium. Particularly useful
for cryogenic applications. |
| 181 |
145E |
145 |
51.2Sn
30.6Pb
18.2Cd |
8.45 |
-- |
0.35 |
24 |
Good
general purpose solder in the medium temperature range. Maintains
its creep strength well. Not applicable against gold. |
| 2 |
154 |
149 |
80In
15Pb
5Ag |
7.85 |
13 |
0.43 |
28 |
Especially
useful for soldering against gold, as leaching is minimized.
Good thermal fatigue properties. Compatible with Indalloy numbers
204, 205, 206, 7, 10 and 150 in step-soldering applications. |
| 4 |
157MP |
-- |
100In |
7.31 |
24 |
0.86 |
29 |
Soft,
ductile metal has good wettability on many surfaces including
ceramics, glass and quartz. Deforms indefinately under load
and has no tendency to become brittle, making it valuable for
cryogenic applications. |
| 97 |
163 |
144 |
43Pb
43Sn
14Bi |
8.99 |
-- |
-- |
-- |
Good
general purpose step soldering alloy. |
| 9 |
167 |
154 |
70Sn
18Pb
12In |
7.79 |
12.2 |
0.45 |
24 |
General
purpose solder in 160 degrees C range with good physical properties. |
| 204 |
175 |
165 |
70In
30Pb |
8.19 |
8.8 |
0.38 |
28 |
Indalloys
#7, #10, #150, #204, #205 and #206 comprise a group of lead-indium
solders designed to cover the temperature range of 165 degrees
C to 275 degrees C. All have the minimum gold-leaching characteristics
of lead-indium as well as good thermal fatigue properties. |
| Sn62 |
179E |
179 |
62Sn
36Pb
2Ag |
8.41 |
11.9 |
0.5 |
27 |
Good
general purpose solder. Can be used on silver bearing surfaces
to reduce scavenging. |
| 205 |
181 |
173 |
60In
40Pb |
8.52 |
7 |
0.29 |
27 |
See
Indalloy #204 above. |
| 106
(Sn63)* |
183E |
183 |
63Sn
37Pb |
8.4 |
11.5 |
0.5 |
25 |
Standard
eutectic tin-lead solder with wide application. Not recommended
against silver and/or gold. |
| 231 |
186 |
174 |
86.5Sn
5.5Zn
4.5In
3.5Bi |
7.36 |
-- |
-- |
-- |
Pb
free solder. High dross. |
| 227 |
187 |
175 |
77.2Sn
20In
2.8Ag |
7.25 |
9.8 |
0.54 |
28 |
Pb
free solder can be used as a replacement for 63Sn 37Pb, 62Sn
36Pb 2Ag and 60Sn 40Pb in that it has similar physical and mechanical
properties. |
| 201 |
199E |
199 |
91Sn
9Zn |
7.27 |
15 |
0.61 |
-- |
Recommended
for soldering to aluminum. Use flux #3. |
| 7 |
210 |
184 |
50In
50Pb |
8.86 |
6 |
0.22 |
27 |
See
Indalloy #204 above. |
| 232 |
217E |
217 |
93.6Sn
4.7Ag
1.7Cu |
7.43 |
-- |
-- |
-- |
Patented
Pb free solder. |
| 121 |
221E |
221 |
96.5Sn
3.5Ag |
7.36 |
16 |
0.33 |
30 |
Standard
tin-silver eutectic solder with wide application when lead-based
solders do not meet temperature, strength or safety requirements.
Not recommended against gold-plated surfaces. Excellent for
step soldering with #42, #106, #165 and #171. |
| 206 |
231 |
197 |
60Pb
40In |
9.3 |
5.2 |
0.19 |
26 |
See
Indalloy #204 above. |
| 238 |
217E |
217 |
90Sn
10Au |
7.78 |
-- |
-- |
-- |
Lower
temp eutectic, in the Au Sn system. |
| 209 |
233MP |
-- |
65Sn
25Ag
10Sb |
7.8 |
-- |
-- |
36 |
Low
temperature die attach alloy. Has very high tensile strength. |
| 3 |
237 |
143 |
90In
10Ag |
7.54 |
22.1 |
0.67 |
15 |
Indium
with silver added to improve strength. Has the wettability and
low-temperature malleability of indium. |
| 133 |
240 |
235 |
95Sn
5Sb |
7.25 |
11.9 |
0.28 |
31 |
Higher
tensile strength solder than #121. Particular application is
joining copper tubing in refigeration and potable water systems.
Has good wettability with good long time sheer strength at 100
degreees C. |
| 236 |
247 |
237 |
83Pb
10Sb
5Sn2
Ag |
10.35 |
-- |
-- |
-- |
Intermediate
temp solder. Creep resistant. |
| 233 |
255 |
245 |
85Pb
10Sb
5Sn |
10.36 |
6 |
-- |
-- |
Intermediate
temp solder. Creep resistant. |
| 10 |
260 |
240 |
75Pb
25In |
9.97 |
4.6 |
0.18 |
26 |
See
Indalloy #204 above. |
| 150 |
275 |
260 |
81Pb
19In |
10.27 |
4.5 |
0.17 |
27 |
See
Indalloy #204 above. Lowest In containing for good wettability. |
| 182 |
280E |
280 |
80Au
20Sn |
14.51 |
-- |
0.57 |
16 |
Eutectic
die attach and package sealing. |
| 151 |
296 |
287 |
92.5Pb
5Sn
2.5Ag |
11.02 |
8.6 |
-- |
29 |
Similar
to Indalloy #165. |
| 228 |
299 |
267 |
88Pb
10Sn
2Ag |
10.75 |
8.5 |
0.27 |
29 |
High
temp solder. |
| 159 |
302 |
275 |
90Pb
10Sn |
10.75 |
8.9 |
0.25 |
29 |
High
temp solder for BGA applications. |
| 237 |
304MP |
-- |
93Pb
3Sn
2In
2Ag |
11.07 |
-- |
-- |
-- |
High
temp solder. |
| 165 |
309E |
309 |
97.5Pb
1.5Ag
1Sn |
11.28 |
6 |
0.23 |
30 |
Standard
lead-silver-tin eutectic solder with wide application in semiconductor
assembly. |
| 164 |
310 |
300 |
92.5Pb
5In
2.5Ag |
11.02 |
5.5 |
0.25 |
25 |
This
alloy is very useful in the 300 degrees C range. It has particularly
good thermal fatigue properties as well as the minimal gold
leaching properties of indium-lead alloys. Often used in reducing
atmospheres. |
| 171 |
312 |
308 |
95Pb
5Sn |
11.06 |
8.8 |
0.23 |
30 |
Wide
application in soldering. |
| 239 |
313E |
313 |
91Pb
4Sn
4Ag
1In |
11.05 |
-- |
-- |
-- |
High
temp solder. |
| 183 |
356E |
356 |
88Au
12Ge |
14.67 |
-- |
0.44 |
13 |
Eutectic
die attach. |
| 178 |
485 |
451 |
82Au
18In |
14.9 |
-- |
-- |
-- |
Stiff
alloy. Limited fabrications available. |
|
|
|
|
|
|
|
|
|
* #106 is compatible with copper
and nickel
|